Removal of cationic dyes from aqueous samples using magnetic Gum Arabic polymer

Introduction: The Earth is composed of 75% water, but only 3% of this is freshwater and merely 1% of that is accessible for human consumption. In most instances humans are the ones responsible for introducing pollutants into water. Dyes are among the most significant pollutants found in textile wastewater. As a result of its economic feasibility and high selectivity adsorption has gained widespread popularity as a technique for treating organic dyes. In this research a novel magnetic adsorbent was developed and utilized to remove certain toxic dyes.
Material and methods: In this research study Gum Arabic has been utilized as a natural and biodegradable polymer for the preparation of an effective adsorbent. To enhance the surface area, efficiency and stability of this natural polymeric adsorbent,,citric acid has been employed as a green crosslinker. According to our findings,,Gum Arabic has been polymerized for the first time with citric acid as a crosslinker and utilized for the removal of cationic dyes. Additionally, a crosslinked Gum Arabic polymer synthesized using citric acid has been incorporated with magnetite nanoparticles, ensuring its facile recovery from the medium upon application of a magnetic field. Furthermore, the prepared magnetic Gum Arabic was employed for the removal of Crystal Violet, Malachite Green, and Methylene Blue dyes from aqueous samples.
Results and discussion: In this study, the impact of various parameters, including initial dye solution concentration, solution pH, contact time between the adsorbent and the dye solution, adsorbent dosage, and dye solution temperature, on the removal efficiency was investigated. According to the results, the adsorption capacity of the adsorbent (CL-GA/Fe3O4) increased with increasing dye solution concentration, reaching its maximum levels of 209.80, 205.12, and 177.12 mg/g for MB, CV, and MG, respectively. Additionally, the removal efficiency for these dyes increased with increasing solution pH, reaching 99.43% (MB), 97.13% (MG), and 96.62% (CV) at a pH of 6. Furthermore, the removal efficiency of dyes increased with increasing adsorption temperature, indicating an endothermic process. It is noteworthy that in this study, both MB and MG dyes reached their maximum removal efficiency of 99.49% and 97.47%, respectively, after 20 min. In contrast, CV reached its maximum removal efficiency of 96.62% within a 15-min time frame. In this investigation, it was observed that the Langmuir model showed a significantly better fit to the adsorption data compared to the Freundlich model, indicating its accuracy in describing monolayer adsorption. Additionally, this study revealed that the obtained adsorption kinetic data fit well with the pseudo-second-order model. This suggests that chemisorption likely plays a significant role in the rate-limiting step of the adsorption process.
Conclusion: In this research, a novel nanoadsorbent (CL-GA/Fe3O4) based on crosslinked Gum Arabic with citric acid and magnetized with Fe3O4 nanoparticles was employed for the removal of cationic dyes. To validate the effectiveness of the (CL-GA/Fe3O4) adsorbent, various characterization techniques, including FT-IR, FESEM, EDX, Zeta potential, and VSM, were employed. The findings of this study demonstrate the development of an innovative and efficient adsorbent for dye removal, which holds significant importance in addressing environmental challenges.